create compile.bat in directory c:/texlive/2019/

"C:\texlive\2019\bin\win32\pdflatex.exe" %1 %2 %3
"C:\texlive\2019\bin\win32\bibtex.exe" %4
"C:\texlive\2019\bin\win32\makeindex.exe" %4
"C:\texlive\2019\bin\win32\pdflatex.exe" %1 %2 %3
"C:\texlive\2019\bin\win32\pdflatex.exe" %1 %2 %3

:: INSTALL PANDOC TO CONVERT TO WORD FILE

::pandoc %3 -S -o %3.docx

:: TO UPDATE REFERENCES 

::set referencefilename=filereference.bib
::pandoc %3 --bibliography=%referencefilename% -S -o %3.docx





::PdfLaTeX+MakeIndex+BibTeX
::$synctexoption
::$fullname
::$basename

do this open texworks

go to file>edit>preferences>typesetting>processing tools

add new processing tool PdfLaTeX+MakeIndex+BibTeX

browse to compile.bat created under c:/texlive/2019/

then add 3 arguments

$synctexoption $fullname $basename

now change defaults to PdfLaTeX+MakeIndex+BibTeX

Do comment if it works for you.